Molecular design and synthesis methods of hands-holding ether
Keywords:
Polyether, Alkyne-containing polymers, Hands-holding ether, Terminal alkyne reaction, Synthesis of Williamson etherAbstract
Polymers play an important role in modern life, in which polyether and alkyne-containing polymers have been widely used in biomedical, optoelectronic and other fields. This paper mainly discusses the molecular design and synthesis of the hands-holding ether which will have a broad application prospect. The key steps are the substitution of diethyl 2-phenylmalonate by Br atom, the reaction of terminal alkyne with Br atom, and Williamson ether synthesis.
References
Stephanie H, C.; James M, Tour. J. Org. Chem. 2003, 68, 8750-8766.
Fernandez-berridi M, J.; Guzman G, M.; Iruin J, J.; Elorza J, M. Polymer 1983, 24, 417-422.
Van Krevelen, D. W. Properties of polymers, 1st ed, Amsterdam: Elsevier, 1972, pp. 388.
Wang, L.; Fang, G.; Cao, D. J. Macromol. Sci. Part A. 2014, 51, 668-681.
Xin, G.; Martin, B.; Klaus, M. Prog. Polym. Sci. 2013, 38, 1832-1908.
Friend, R.; Gymer, R.; Holmes, A. Nature 1999, 397, 121-128.
Von der Ehe, C.; Kempe, K.; Bauer, M.; Baumgaertel, A.; Hager, M. D.; Fischer, D.; Schubert, U. S. Macromol. Chem. Phys. 2012, 213, 2146-2156.
Liu, Y. J.; Jacky W, Y. L.; Tang, B. Z. Natl. Sci. Rev. 2015, 2, 493-509.
He, B. Z.; H, J. C.; Liu, X. Y.; Zhang, J.; Jacky W, Y. L.; Tang, B. Z. Prog. Polym. Sci. 2022, 126, 101503.
Tajbakhsh, M.; Khazaei, A.; Mahalli, M. S.; Vaghi, R. G. Phosphorus Sulfur Silicon Relat. Elem. 2004, 179, 1159-1163.
Lafaquiere, V.; Barbe, S.; Puech-Gueot, S.; Guieysse, D.; Cortes, J.; Monsan, P.; Simeon, T.; Andre, I.; Remaud-simeon, M. Chembiochem 2009, 10, 2760-2771.
Pehlivan, L.; Metay, E.; Delbrayelle, D.; Mignani, G.; Lemaire, M. Eur. J. Org. Chem. 2012, 2012, 4689-4693.
Wang, F.; Zhou, Q. Z.; Zhu, K. L.; Li, S. J.; Wang, C.; Liu, M.; Li, N.; Fronczek, F. R.; Huang, F. H. Tetrahedron 2009, 65, 1488-1494.
Huang, X. J.; Bugarin, A. Chem. Eur. J. 2016, 22, 12696-12700.
Yamada, K.; Nakano, M.; Maekawa, M.; Akindele, T.; Tomioka, K. Org. Lett. 2018, 10, 3805-3808.
Jammi, S.; Mouysset, D.; Siri, D.; Bertrand, M. P.; Feray, L. J. Org. Chem. 2013, 78, 1589-1603.
Fan, C.; Hou, J.; Chen, Y. J.; Ding, K. L.; Zhou, Q. L. Org. Lett. 2021, 23, 2074-2077.
