Molecular Design of Carbene Catalyst Intermediates with Ceiling Fan Structure

Authors

  • SUSU ZHANG 中国人民大学
  • YouYue Yao

Keywords:

Molecular design, Carbene, Diels-Alder reaction, Friedel-Crafts alkylation

Abstract

Through Friedel-Crafts alkylation and D-A reaction, a fan-like carbene synthesis intermediate molecule is obtained, which plays an important role in the synthesis of metal carbene complexes.

References

Nishimura, G.; Shiraishi, Y.; Hirai, T. Chem. Commun. 2005, 1, 5313-5315.

Wongkongkatep, J.; Miyahara, Y.; Ojida, A. Angew. Chem. Int. Ed. 2006, 45, 665-668.

Wang, L. D.; Duan, L.; Lei, G. T. Jpn. Appl. Phys. 2004, 43, 560-562.

Ha, J.; Vacha, M.; Khanchaitit, P. Synth. Met. 2004, 144, 151-158.

Akkattu, T. Biju. N-heterocyclic Carbenes in Organocatalysis, Wiley-VCH, India, 2019, pp. 1-20.

Wolthuis, E. J. Org. Chem., 1961, 26, 2215-2220.

Gong, Y.; Zhou, Y. C.; Qin J. B. J. Mol. Struct. 2010, 963, 76-81.

Huang, J. Ph.D. Dissertation, Guangdong Pharmaceutical University, Guangzhou, 2019, 28-29(in Chinese).

(黄菊, 博士论文, 广东药科大学, 广州, 2019, 28-29.)

Ye, J. X.; Sun, J.; Wang, X.; Zhou, M. D. J. Pet. Technol., 2017, 37, 15.

Wang, J. X.; Jing, B.; Hou, X. W.; Li, X. Y.; Shi, H. Y.; Xiong, X. Q.; Cheng, L. J. Huaqiao Univ., 2010, 31, 645-648(in Chinese).

(汪家喜, 荆彬, 侯晓伟, 李晓燕, 石慧英, 熊兴泉, 程琳, 华侨大学报, 2010, 31, 645-648.)

Liu, J. C.; Cheng, L., Huaqiao Univ., 2012, 33, 518-519(in Chinese).

(刘嘉川, 程琳, 华侨大学报, 2012, 33, 518-519.)

Sisido, K.; Odo, Y.; Nakamura, T.; Nozaki, H. J. Am. Chem. Soc. 1961, 26, 1368.

Godinez, C. E.; Zepeda, G.; Mortko, C. J.; Dang, H.; Garcia-Garibay, M. A. J. Org. Chem. 2004, 69, 1652-1662.

Molecular “Ceilifan” and a picture of reality

Published

2022-08-12

How to Cite

ZHANG, S., & Yao, Y. (2022). Molecular Design of Carbene Catalyst Intermediates with Ceiling Fan Structure. Molecular Design, 1(1), 18–20. Retrieved from http://chemgroups.ruc.edu.cn/VJFE/index.php/MOLD/article/view/29

Issue

Section

Communications