http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE <p>JACS(FAKE), 全称为Journal of Academic Chemists’ Start (For Academic Knowledge Exercises)，中文全称为《学院派化学家之开端杂志(用于学术知识训练)》，标准缩写为J. Acad. Chem. Start。 2021年6月建立，主要服务于人大本科专业选修课《化学信息学》的课程实践教学，是教学虚拟期刊(VJFE)的第一本虚拟期刊。</p> 中国人民大学化学系 zh-CN JACS(FAKE) http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE/article/view/3 <p>本期需要主要介绍了本杂志的出发点、稿件产生的过程与本期相关编辑活动及人员。</p> 泳霖 贺 ##submission.copyrightStatement## 2021-07-01 2021-07-01 1 1 1 1 http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE/article/view/9 ruc ruc ##submission.copyrightStatement## 2021-07-01 2021-07-01 1 1 http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE/article/view/8 楠 张 泳霖 贺 ##submission.copyrightStatement## 2021-07-01 2021-07-01 1 1 http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE/article/view/5 <p>本文介绍了以甲基咪唑为基础和吡咯基团以烷基链相连的功能化离子液体的合成方法，以3-(8-(1-吡咯)辛基)-1-甲基咪唑六氟磷酸盐(3-(8-(1<em>H</em>-pyrrol-1-yl)octyl)-1-methyl-1<em>H</em>-imidazol-3-ium hexafluorophosphate, [Py-C8-MIm]PF₆)为例，通过三步反应合成了该物质，之后又对其衍生物的合成作了一些分析。</p> 港 张 ##submission.copyrightStatement## 2021-07-01 2021-07-01 1 1 2 3 http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE/article/view/7 <p>Because of the advantages of flexibility and self-healing, ionic liquids are becoming intriguing electronic materials for flexible and stretchable electronics. We designed a new kind of light-sensitive ionic liquid with rapid response in the ranges from visible to near-infrared light, which had great potential in the fabrication of optoelectronic devices. A polypyrrole oligomer was introduced to an imidazolium-based ionic liquid and they were covalently linked to each other by alkyl chain of eight carbon atoms. The photothermal conversion of polypyrrole and the electric response of imidazolium were combined to realize the function of light-sensing. Herein, we presented the synthetic route of the precursor 1-[8-(N-Pyrrolyl)octyl]-3-methylimidazolium hexafluophosphate, from commercially available materials pyrrole, 1-methylimidazole, 1,8-dibromooctane and ammonium hexanfluophosphate. NMR spectroscopy was used to confirm the structures.</p> Xintong Liu ##submission.copyrightStatement## 2021-07-01 2021-07-01 1 1 4 5 http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE/article/view/11 <p>这篇文章报道了以市售的吡咯、N-甲基咪唑以及 1, 8-二溴辛烷经过两步反应合成[Py-C₈-MIm]Br离子液体，并通过离子交换反应将阴离子置换为[PF₆]^-的方法。这是一条一般路线，通过简单地改变溴代烷的烷基链长度，可适用于 C₄~C₁₂的情况。</p> Qianci Wang ##submission.copyrightStatement## 2021-07-01 2021-07-01 1 1 6 7 http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE/article/view/10 <p>在本篇文章中，我们设计合成并报道了一种新型的 [Py-C8-MIM][PF6-]离子液体，该离子液体阳离子通过1-甲基咪唑、吡咯以及1,8-二溴辛烷三种分子合成，并且由于1-甲基咪唑与吡咯分子组成的两端基具有良好的光热光电性能，该离子液体在光热光电等诸多方面均有着广阔的前景。</p> 楠 张 ##submission.copyrightStatement## 2021-07-01 2021-07-01 1 1 8 9 http://chemgroups.ruc.edu.cn/VJFE/index.php/JACS-FAKE/article/view/4 <p>本文主要介绍了一种功能化咪唑基离子液体(PyC₈MIM⁺PF₆^-)的合成方法，在该合成路线中，利用吡咯的亲核性，与卤代烷烃发生取代反应生成反应前体，再与甲基咪唑取代后生成双核阳离子的离子液体，再通过阴离子交换便能得到含PF₆^-的离子液体。该离子液体在光热转化方面的性能和导电能力都十分良好，其聚合物在纳米电子和光电子器件领域也有着重要的应用。</p> 宇航 杨 ##submission.copyrightStatement## 2021-07-01 2021-07-01 1 1 10 11